The effect of thermal treatment on the 57Fe Mössbauer spectrum of beryl     

Geraldo Magela da Costa  Gabriel de Oliveira Polli  Márcio A. Kahwage  Eddy de Grave  Antônio Claret Soares Sabioni  Júlio Cesar Mendes 《Physics and Chemistry of Minerals》2006,33(3):161-166

Mössbauer spectra (MS) of blue, green and yellow beryl (ideally Be₃Al₂Si₆O₁₈) containing approximately 1% of iron were obtained at 295 and 500 K. Room temperature (RT) spectra of both blue and green samples showed the presence of an asymmetric Fe²⁺ doublet (ΔE _Q~2.7 mm/s, δ~1.1 mm/s), with a very broad low-velocity peak. There is no clear evidence for the presence of a ferric component. The MS of the yellow sample at RT consists of an intense central absorption with parameters typical for Fe³⁺ (ΔE _Q~0.4 mm/s, δ~0.29 mm/s), plus an apparently symmetrical Fe²⁺ doublet. This sample acquires a light-blue shade upon heating in air at about 620 K. Thermal treatments at high temperatures caused no significant changes in the MS, but the green and yellow beryl acquire a blue colour. All these results are interpreted in relation to the existence of channel water and the distribution of iron among the available crystallographic sites.  相似文献   

Reviews on books, internet and scientific media     

J. Rasanen  Fakhry A. Assaad  A. M. de Grosbois 《Environmental Geology》2006,51(4):655-657

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Book Reviews     

Jörg Matschullat  Anne Marie de Grosbois  Fakhry A Assaad 《Environmental Geology》2006,49(8):1224-1225

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Spatial assessment and redesign of a groundwater quality monitoring network using entropy theory, Gaza Strip, Palestine   总被引：3，自引：0，他引：3  

Y. Mogheir  V. P. Singh  J. L. M. P. de Lima 《Hydrogeology Journal》2006,14(5):700-712

Using entropy theory, a methodology was developed for the evaluation and redesign of groundwater quality monitoring wells in the Gaza Strip in Palestine. Essential to the methodology is the development of a Transinformation Model (TM) which yields the amount of information transfer and the dependency between the wells as a function of distance. The TM parameters, such as the minimum transinformation and the range, were employed for evaluating the network which revealed that most of the distances between wells were less than the range. It also indicated that a high percentage of redundant information existed in the network. Therefore, the network was reduced by superimposing a square pattern over the monitored area and selecting one well per square block in a stratified pattern. The methodology was tested using the chloride data collected from 1972–2000 from 417 groundwater quality monitoring wells in the Gaza Strip. The number of the groundwater quality monitoring wells in the Gaza Strip was reduced by 53%, while there was 26% redundant information based on the minimum existing distance between wells. This methodology is meant to help monitor the groundwater quality (salinity) in the Gaza Strip.  相似文献   

DMS and SO2 at Baring Head, New Zealand: Implications for the Yield of SO2 from DMS     

Warren J. de Bruyn  Mike Harvey  Jill M. Cainey  Eric S. Saltzman 《Journal of Atmospheric Chemistry》2002,41(2):189-209

Atmospheric dimethyl sulfide (DMS) and sulfur dioxide (SO₂) concentrations were measured at Baring Head, New Zealandduring February and March 2000. Anti-correlated DMS and SO₂ diurnalcycles, consistent with the photochemical production of SO₂ from DMS, were observed in clean southerly air off the ocean. The data is used to infer a yield of SO₂ from DMS oxidation. The estimated yields are highly dependent on assumptions about the DMS oxidation rate. Fitting the measured data in a photochemical box model using model-generated OH levels and the Hynes et al. (1986) DMS + OH rate constant suggests that theSO₂ yield is 50–100%, similar to current estimates for the tropical Pacific.However, the observed amplitude of the DMS diurnal cycle suggests that the oxidation rate is higher than that used by the model, and therefore, that theSO₂ yield is lower in the range of 20–40%.  相似文献   

贵州关岭生物群中植物化石的发现及其意义   总被引：4，自引：1，他引：4  

孟繁松  汪啸风  陈孝红  陈辉明  张振来  徐光洪  陈立德  王传尚  孙亚莉 《地层学杂志》2002,26(3):170-172,T001,T002

关岭生物群是近年来在我国贵州关岭地区瓦窑组中发现的一个十分重要的生物群 ,其中的植物化石经研究计有 Equisetites cf.arenaceus(Jaeger) Bronn.、Ctenozamitessarrani Zeiller。依据植物化石 C.sarrani常见于晚三叠世和 E.cf.arenaceus系似木贼属中较古老的类型 ,指出含植物化石的地层时代为晚三叠世卡尼期。瓦窑组系海相沉积 ,其中的植物化石无疑为异地埋藏 ,但从化石通常保存尚好来看 ,估计搬运的距离不会很远 ,它们可能是从距海岸不远的陆地被河流带到较平静的海湾或海槽而沉积下来的。此外 ,从该组植物茎干化石具清楚的年轮分析 ,推测卡尼期时 ,贵州关岭一带为非热带雨林地区 ,一年中气候不是四季如一 ,而是有明显的季节变化  相似文献   

国际冰芯与气候环境研究新进展--关于国际"冰芯与气候"会议     

姚檀栋  王宁练  任贾文  侯书贵  效存德  叶玉江 《冰川冻土》2002,24(6):806-811

2001年8月19～23日, 在格陵兰举行了规模空前的"冰芯与气候"国际盛会, 会议展示了冰芯与气候环境研究的最新进展. 文中介绍这次会议并概括了近年来的主要研究进展. 与南北极地区的冰芯研究相比, 中低纬度地区冰芯研究是近年来国际冰芯研究中发展最快的. 在这一研究中, 中国科学家做出了重要贡献并得到了国际同行的高度评价.  相似文献   

运用层序不对称性分析海平面变化特征     

周雁  陈洪德  王成善  王正元  梁西文  文可东 《矿物岩石》2002,22(2):58-63

目前研究海平面变化的方法尚不能精确确定海平面变化，对记录海平面变化的沉积体或层序物质组成及结构特点的研究尚显薄弱。在分析层序不对称性与海平面变化的关系基础，提出层序不对称系数S0，认为海平面的升降变化对浅水沉积区影响显著，其结果必然造成层序S0的增加；海平面的升降变化对沉水沉积区影响不大，层序S0较为恒定。对进行详细研究中扬子区S0分布特点，运用S0曲线计算了中扬子区海平面变化特点，并与其他方法进行对比，认为可以用S0判断水体相对深浅，分析海平面变化。  相似文献   

地幔热柱及其成矿作用研究     

牛树银  孙爱群  谢汝斌  许传诗  王宝德  杨志宏  毕伏科  孙冀凡 《华北地质》2002,25(1):11-22

成矿作用研究表明 ,在地球的演化历史中 ,成矿数量有从少到多 ,聚矿能力有由弱到强的演化趋势。中生代为全球规模的成矿大爆发阶段 ,究其原因可能与地球的发展演化密切相关。地球形成的早期 ,由于地球物质尚未充分分异 ,成矿强度不大。当然 ,有部分在地球演化早期形成的矿床 ,在后来的多次构造改造过程中被改造迁移 ,甚至消失。中生代地球进入了一个强烈的地幔热柱活动时期 ,聚集于D”层及外核的成矿物质可通过地幔热柱多级演化向上迁移 ,并在幔枝构造的有利构造扩容带中成矿 ,幔枝构造则成为中生代主要的成矿控矿构造类型  相似文献   

Geochemistry and Rb–Sr geochronology of a ductile shear zone in the Orlica-Śnieżnik dome (West Sudetes, Poland)     

Ulrich Lange  Michael Bröcker  Klaus Mezger  Jerzy Don 《International Journal of Earth Sciences》2002,91(6):1005-1016

Amphibolite-facies orthogneisses of the Orlica-vnie™nik dome in the West Sudetes (Poland) show a local continuous transition from weakly deformed augen gneisses to finely laminated mylonites. Field evidence indicates that ductile shearing developed pre- or syntectonically to a migmatization event. Bulk-rock compositions of variably deformed samples yield no indications for deformation- and/or fluid-enhanced element mobility and redistribution. ⁸⁷Rb-⁸⁶Sr geochronology (biotite, phengite, whole rock) places time constraints on the deformation process and the post-orogenic cooling history. Phengite- and biotite-whole-rock pairs yield Rb-Sr ages of 340 to 334 Ma and 335 to 294 Ma, respectively, independent of the degree of deformation. The weighted mean of phengite-whole-rock pairs indicates an age of 337.4DŽ.3 Ma. Combining most of the biotite-whole-rock data yields a weighted mean age of 328.6dž.4 Ma. Because of their different closure temperatures for the Rb-Sr system, these differences are interpreted to date cooling after a thermal event. Direct dating of the deformation is not possible, but the cooling history record defines a minimum age for the development of ductile shearing and the last migmatization event. These time constraints provide evidence for the initiation of crustal collapse during or immediately following peak metamorphic conditions. The results of this study further document the importance of Variscan metamorphism in the Orlica-vnie™nik dome.  相似文献